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Spatial targeting evaluation of energy and environmental performance of waste-to-energy processing

Petar S. Varbanov, Timothy G. Walmsley, Yee V. Fan, Jiří J. Klemeš, Simon J. Perry

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 731-744 doi: 10.1007/s11705-018-1772-1

摘要：

Waste-to-energy supply chains are important potential contributors to minimising the environmental impacts of municipal solid waste by reducing the amounts of waste sent to landfill, as well as the fossil fuel consumption and environmental footprints. Accounting for the spatial and transport properties of the waste-to-energy supply chains is crucial for understanding the problem and improving the supply chain designs. The most significant challenge is the distributed nature of the waste generation and the household energy demands. The current work proposes concepts and a procedure for targeting the size of the municipal solid waste collection zone as the first step in the waste-to-energy supply chains synthesis. The formulated concepts and the provided case study reveal trends of reducing the net greenhouse gas savings and energy recovery by increasing the collection zone size. Population density has a positive correlation with the greenhouse gas saving and energy recovery performance. For smaller zone size the energy recovery from waste approaches and in some cases may surpass the energy spent on waste transportation. The energy recovery and greenhouse gas savings remain significant even for collection zones as large as 200 km2. The obtained trends are discussed and key directions for future work are proposed.

关键词： waste-to-energy     supply chain optimisation     GHG savings     energy recovery ratio    

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Energy neutrality potential of wastewater treatment plants: A novel evaluation framework integratingenergy efficiency and recovery

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1549-0

摘要：

• Framework of indicators was established based on energy efficiency and recovery.

关键词： Wastewater treatment plants     Energy neutrality potential     Energy efficiency     Energy recovery     Evaluation framework    

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A Novel Electrochemical Reactor for Nitrogen and Phosphorus Recovery from Domestic Wastewater

Shiting Ren, Mengchen Li, Jianyu Sun, Yanhong Bian, Kuichang Zuo, Xiaoyuan Zhang, Peng Liang, Xia Huang

《环境科学与工程前沿（英文）》 2017年 第11卷 第4期 doi: 10.1007/s11783-017-0983-x

摘要： To separate and concentrate NH4+ and PO43 from the synthetic wastewater to the concentrated solution through a novel electrochemical reactor with circulated anode and cathode using the difference of the concentration between electrode chamber and middle chamber. In recent years, the research on electrochemical processes have been focused on phosphate and ammonium removal and recovery. Among the wide range of possibilities with regards to electrochemical processes, capacitive deionization (CDI) saves the most energy while at the same time does not have continuity and selectivity. In this study, a new electrochemical reactor with electrolyte cyclic flowing in the electrode chambers was constructed to separate and concentrate phosphate and ammonium continuously and selectively from wastewater, based on the principle of CDI. At the concentration ratio of NaCl solution between the electrode chambers and the middle chamber (r) of 25 to 1, phosphate and ammonium in concentration level of domestic wastewater can be removed and recovered continuously and selectively as struvite. Long-term operation also indicated the ability to continuously repeat the reaction and verified sustained stability. Further, the selective recovery at the certain r could also be available to similar technologies for recovering other kinds of substances.

关键词： Nutrients recovery     Electrochemical reactor     Electrolyte cyclic flowing     Concentration ratio     Struvite    

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“NEW” resource recovery from wastewater using bioelectrochemical systems: Moving forward with functions

Akshay Jain, Zhen He

《环境科学与工程前沿（英文）》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1052-9

摘要：

Resource recovery from wastewater is a key function of bioelectrochemical systems.

NEW resources to recover include Nutrient, Energy, and Water.

Identifying proper application niches can guide BES research and development.

More efforts should be invested to the application of recovered resources.

A mindset for energy performance and system scaling is critically important.

关键词： Bioelectrochemical systems     Resource recovery     Wastewater treatment     Energy     Nutrients    

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山西沁水盆地柿庄北区块3#煤层注入埋藏CO2提高煤层气采收率试验和评价

叶建平,张兵,Sam Wong

《中国工程科学》 2012年 第14卷 第2期   页码 38-44

摘要：

对沁水盆地南部柿庄北区块进行了深煤层注入地质和工程评价，认为柿庄北区块适合进行深煤层注入CO2开采煤层气技术的应用；通过SX-001井的微型先导性试验，对SX-001井的注入前后产气量与产水量、气体成分变化和井底压力变化规律进行了总结。通过现场试验，注入CO2后SX-001井的产气量是注入前的2.45倍；在小于煤岩破裂压力的条件下，每天注入20 t的CO2能够实现顺利注入，并且压力上升速度较慢；注入CO2后，煤岩发生膨胀，局部煤层的渗透率降低，排采一段时间后恢复；在目的煤层中注入的CO2的影响范围内，烃类气体总的置换效率达到14.18 cm3/g。该试验成果证明柿庄北区块通过注入CO2开采煤层气实现了CO2的埋藏，提高了煤层气井的采收率。

关键词： 山西沁水盆地     注入CO2     煤层气     采收率    

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Improved energy recovery from dark fermented cane molasses using microbial fuel cells

Soumya Pandit, Balachandar G, Debabrata Das

《化学科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 43-54 doi: 10.1007/s11705-014-1403-4

摘要： A major limitation associated with fermentative hydrogen production is the low substrate conversion efficiency. This limitation can be overcome by integrating the process with a microbial fuel cell (MFC) which converts the residual energy of the substrate to electricity. Studies were carried out to check the feasibility of this integration. Biohydrogen was produced from the fermentation of cane molasses in both batch and continuous modes. A maximum yield of about 8.23 mol H /kg COD was observed in the batch process compared to 11.6 mol H /kg COD in the continuous process. The spent fermentation media was then used as a substrate in an MFC for electricity generation. The MFC parameters such as the initial anolyte pH, the substrate concentration and the effect of pre-treatment were studied and optimized to maximize coulombic efficiency. Reductions in COD and total carbohydrates were about 85% and 88% respectively. A power output of 3.02 W/m was obtained with an anolyte pH of 7.5 using alkali pre-treated spent media. The results show that integrating a MFC with dark fermentation is a promising way to utilize the substrate energy.

关键词： dark fermentation     biohydrogen     microbial fuel cell     volatile fatty acid     anolyte    

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Concentrating aqueous hydrochloric acid by multiple-effect membrane distillation

Rongling LIU, Yingjie QIN, Xiaojun LI, Liqiang LIU

《化学科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 311-321 doi: 10.1007/s11705-012-1207-3

摘要： Multiple-effect membrane distillation (MEMD) using a hollow fiber-based air-gap membrane distillation module was experimentally examined for concentrating dilute aqueous hydrochloric acid. The effects of the hot and cold feed-in temperatures, and the feed-in volumetric flow rates on the performance of the MEMD process were studied. The performance was evaluated using the performance ratio ( ), the average selectivity of water over HCl ( ) and the permeation flux ( ). Two types of porous fibers made from polypropylene were used to fabricate the MEMD modules. The experimental data indicated that hollow fibers with high porosity were preferred for the MEMD process. The , and all decreased as the feed concentration increased. When the feed concentration was below 12 wt-%, the was 6.0 – 9.6 and was 10 – 190. When the concentration of HCl reached 18 wt-%, the and were about 4.4 and 2.3, respectively. However, sharply decreased to around 1.0 when the feed was further concentrated. During an operational stability test that lasted for 30 days, the performance of the MEMD modules remained good.

关键词： multiple-effect membrane distillation     performance ratio     hydrochloric acid     recovery     stability    

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Heating energy performance and part load ratio characteristics of boiler staging in an office building

Da Young LEE, Byeong Mo SEO, Yeo Beom YOON, Sung Hyup HONG, Jong Min CHOI, Kwang Ho LEE

《能源前沿（英文）》 2019年 第13卷 第2期   页码 339-353 doi: 10.1007/s11708-018-0596-5

摘要： Commercial buildings account for significant portions of the total building energy in South Korea and thus a variety of research on the boiler operation related to heating energy in office buildings has been carried out thus far. However, most of the researches have been conducted on the boiler itself, i.e., the part load ratio characteristics and the corresponding gas energy consumption patterns are not analyzed in the existing studies. In this study, the part load ratio and the operating characteristics of gas boiler have been analyzed within an office building equipped with the conventional variable air volume system. In addition, the gas consumption among different boiler staging schemes has been comparatively analyzed. As a result, significant portions of total operating hours, heating load and energy consumption has been found to be in a part load ratio range of 0 through 40% and thus energy consumption is significantly affected by boiler efficiency at low part load conditions. This suggests that boiler operation at the part load is an important factor in commercial buildings. In addition, utilizing sequential boiler staging scheme can save a gas usage of about 7%. For annual heating energy saving, applying the sequential control boiler with a 3:7 proportion staging is considered to be the optimal control algorithm for maximum efficiency of boilers.

关键词： EnergyPlus     boiler     part load ratio     gas consumption     office building     boiler staging    

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Early-life famine exposure, adulthood obesity patterns, and risk of low-energy fracture

《医学前沿（英文）》 doi: 10.1007/s11684-023-1023-9

摘要： Malnutrition in early life increases the risk of osteoporosis, but the association of early-life undernutrition combined with adulthood obesity patterns with low-energy fracture remains unknown. This study included 5323 community-dwelling subjects aged ≥40 years from China. Early-life famine exposure was identified based on the participants’ birth dates. General obesity was assessed using the body mass index (BMI), and abdominal obesity was evaluated with the waist-to-hip ratio (WHR). Low-energy fracture was defined as fracture occurring after the age of 40 typically caused by falls from standing height or lower. Compared to the nonexposed group, the group with fetal, childhood, and adolescence famine exposure was associated with an increased risk of fracture in women with odds ratios (ORs) and 95% confidence intervals (CIs) of 3.55 (1.57–8.05), 3.90 (1.57–9.71), and 3.53 (1.05–11.88), respectively, but not in men. Significant interactions were observed between fetal famine exposure and general obesity with fracture among women (P for interaction = 0.0008). Furthermore, compared with the groups with normal BMI and WHR, the group of women who underwent fetal famine exposure and had both general and abdominal obesity had the highest risk of fracture (OR, 95% CI: 3.32, 1.17–9.40). These results indicate that early-life famine exposure interacts with adulthood general obesity and significantly increases the risk of low-energy fracture later in life in women.

关键词： famine     obesity     body mass index     waist-to-hip ratio     low-energy fracture    

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Co-application of energy uncoupling and ultrafiltration in sludge treatment: Evaluations of sludge reduction, supernatant recovery and membrane fouling control

An Ding, Yingxue Zhao, Zhongsen Yan, Langming Bai, Haiyang Yang, Heng Liang, Guibai Li, Nanqi Ren

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1238-9

摘要： Effects of metabolic uncouplers addition on sludge reduction were carried out. TCS addition effectively inhibited ATP synthesis and reduced sludge yield. The effluent quality such as TOC and ammonia deteriorated but not significantly. Suitable dosage retarded biofouling during sludge water recovery by UF membrane. Energy uncoupling is often used for sludge reduction because it is easy to operate and does not require a significant amount of extra equipments (i.e. no additional tank required). However, over time the supernatant extracted using this method can deteriorate, ultimately requiring further treatment. The purpose of this study was to determine the effect of using a low-pressure ultrafiltration membrane process for sludge water recovery after the sludge had undergone an energy uncoupling treatment (using 3,3′,4′,5-tetrachlorosalicylanilide (TCS)). Energy uncoupling was found to break apart sludge floc by reducing extracellular polymeric substances (EPS) and adenosine triphosphate (ATP) content. Analysis of supernatant indicated that when energy uncoupling and membrane filtration were co-applied and the TCS dosage was below 30 mg/L, there was no significant deterioration in organic component removal. However, ammonia and phosphate concentrations were found to increase as the concentration of TCS added increased. Additionally, due to low sludge concentrations and EPS contents, addition of 30–60 mg/L TCS during sludge reduction increased the permeate flux (two times higher than the control) and decreased the hydraulic reversible and cake layer resistances. In contrast, high dosage of TCS aggravated membrane fouling by forming compact fouling layers. In general, this study found that the co-application of energy uncoupling and membrane filtration processes represents an effective alternative method for simultaneous sludge reduction and sludge supernatant recovery.

关键词： Sludge reduction     Energy uncoupling     Ultrafiltration membrane     Membrane fouling    

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农业生态工程中人工辅助能产投比的计算分析研究

卞有生,柳英昆,卞晶

《中国工程科学》 2006年 第8卷 第8期   页码 28-32

摘要：

人工辅助能产投比的高低从总体上反映了农业生态系统的功能和生产效率，是系统结构功能的体现，是评价农业生态工程的重要指标。文章以河南新县10户农民为案例，具体介绍了人工辅助能产投比的计算研究方法，并报告了连续3年的研究结果。

关键词： 农业生态工程     能量产投比    

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Organics Recovery from Waste Activated Sludge In-situ Driving Efficient Nitrogen Removal from MatureLandfill Leachate: An Innovative Biotechnology with Energy Superiority

Fangzhai Zhang,Shang Ren,Haoran Liang,Zhaozhi Wang,Ying Yan,Jiahui Wang,Yongzhen Peng,

《工程（英文）》 doi: 10.1016/j.eng.2023.03.005

摘要： The sustainable recovery and utilization of sludge bioenergy within a circular economy context has drawn increasing attention, but there is currently a shortage of reliable technology. This study presents an innovative biotechnology based on free nitrous acid (FNA) to realize sustainable organics recovery from waste activated sludge (WAS) in-situ, driving efficient nitrogen removal from ammonia rich mature landfill leachate by integrating partial nitrification, fermentation, and denitrification process (PN/DN–F/DN). First, ammonia ((1708.5 ± 142.9) mg·L−1) in mature landfill leachate is oxidized to nitrite in the aerobic stage of a partial nitrification coupling denitrification sequencing batch reactor (PN/DN-SBR), with nitrite accumulation ratio of 95.4% ± 2.5%. Then, intermediate effluent (NO2−–N = (1196.9 ± 184.2) mg·L−1) of the PN/DN-SBR, along with concentrated WAS (volatile solids (VSs) = (15119.8 ± 2484.2) mg·L−1), is fed into an anoxic reactor for fermentation coupling denitrification process (F/DN-SBR). FNA, the protonated form of nitrite, degrades organics in the WAS to the soluble fraction by the biocidal effect, and the released organics are utilized by denitrifiers to drive NOx− reduction. An ultra-fast sludge reduction rate of 4.89 kg·m−3·d−1 and nitrogen removal rate of 0.46 kg·m−3·d−1 were realized in the process. Finally, F/DN-SBR effluent containing organics is refluxed to PN/DN-SBR for secondary denitrification in the post anoxic stage. After 175 d operation, an average of 19350.6 mg chemical oxygen demand organics were recovered per operational cycle, with 95.2% nitrogen removal and 53.4% sludge reduction. PN/DN–F/DN is of great significance for promoting a paradigm transformation from energy consumption to energy neutral, specifically, the total benefit in equivalent terms of energy was 291.8 kW·h·t−1 total solid.

关键词： Waste activated sludge     Bioresource recovery     Simultaneous treatment of wastewater and sludge     Mature landfill leachate     Free nitrous acid    

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An investigation of reaction furnace temperatures and sulfur recovery

S. ASADI, M. PAKIZEH, M. POURAFSHARI CHENAR

《化学科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 362-371 doi: 10.1007/s11705-011-1106-z

摘要： In a modern day sulfur recovery unit (SRU), hydrogen sulfide (H S) is converted to elemental sulfur using a modified Claus unit. A process simulator called TSWEET has been used to consider the Claus process. The effect of the H S concentration, the H S/CO ratio, the input air flow rate, the acid gas flow of the acid gas (AG) splitter and the temperature of the acid gas feed at three different oxygen concentrations (in the air input) on the main burner temperature have been studied. Also the effects of the tail gas ratio and the catalytic bed type on the sulfur recovery were studied. The bed temperatures were optimized in order to enhance the sulfur recovery for a given acid gas feed and air input. Initially when the fraction of AG splitter flow to the main burner was increased, the temperature of the main burner increased to a maximum but then decreased sharply when the flow fraction was further increased; this was true for all three concentrations of oxygen. However, if three other parameters (the concentration of H S, the ratio H S/CO and the flow rate of air) were increased, the temperature of the main burner increased monotonically. This increase had different slopes depending on the oxygen concentration in the input air. But, by increasing the temperature of the acid gas feed, the temperature of the main burner decreased. In general, the concentration of oxygen in the input air into the Claus unit had little effect on the temperature of the main burner (This is true for all parameters). The optimal catalytic bed temperature, tail gas ratio and type of catalytic bed were also determined and these conditions are a minimum temperature of 300°C, a ratio of 2.0 and a hydrolysing Claus bed.

关键词： Claus unit     concentration of H2S     tail gas ratio     sulfur recovery     catalytic bed    

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On water security, sustainability, and the water-food-energy-climate nexus

Michael Bruce BECK, Rodrigo VILLARROEL WALKER

《环境科学与工程前沿（英文）》 2013年 第7卷 第5期   页码 626-639 doi: 10.1007/s11783-013-0548-6

摘要： The role of water security in sustainable development and in the nexus of water, food, energy and climate interactions is examined from the starting point of the definition of water security offered by Grey and Sadoff. Much about the notion of security has to do with the presumption of scarcity in the resources required to meet human needs. The treatment of scarcity in mainstream economics is in turn examined, therefore, in relation to how each of us as individuals reconciles means with ends, a procedure at the core of the idea of sustainable development. According to the Grey-Sadoff definition, attaining water security amounts to achieving basic, single-sector water development as a precursor of more general, self-sustaining, multi-sectoral development. This is consistent with the way in which water is treated as “first among equals”, i.e. privileged, in thinking about what is key in achieving security around the nexus of water, food, energy and climate. Cities, of course, are locations where demands for these multiple resource-energy flows are increasingly being generated. The paper discusses two important facets of security, i.e., diversity of access to resources and services (such as sanitation) and resilience in the behavior of coupled human-built-natural systems. Eight quasi-operational principles, by which to gauge nexus security with respect to city buildings and infrastructure, are developed.

关键词： cities as forces for good     diversity     energy and nutrient recovery     green economy     infrastructure failure     resilience    

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ZnO nanorefrigerant in R152a refrigeration system for energy conservation and green environment

D. SENDIL KUMAR,R. ELANSEZHIAN

《机械工程前沿（英文）》 2014年 第9卷 第1期   页码 75-80 doi: 10.1007/s11465-014-0285-y

摘要：

In this paper the reliability and performance of a vapour compression refrigeration system with ZnO nanoparticles in the working fluid was investigated experimentally. Nanorefrigerant was synthesized on the basis of the concept of the nanofluids, which was prepared by mixing ZnO nanoparticles with R152a refrigerant. The conventional refrigerant R134a has a global warming potential (GWP) of 1300 whereas R152a has a significant reduced value of GWP of 140 only. An experimental test rig is designed and fabricated indigenously in the laboratory to carry out the investigations. ZnO nanoparticles with refrigerant mixture were used in HFC R152a refrigeration system. The system performance with nanoparticles was then investigated. The concentration of nano ZnO ranges in the order of 0.1% v, 0.3% v and 0.5%v with particle size of 50 nm and 150 g of R152a was charged and tests were conducted. The compressor suction pressure, discharge pressure and evaporator temperature were measured. The results indicated that ZnO nanorefrigerant works normally and safely in the system. The ZnO nanoparticle concentration is an important factor considered for heat transfer enhancement in the refrigeration system. The performance of the system was significantly improved with 21% less energy consumption when 0.5%v ZnO-R152a refrigerant. Both the suction pressure and discharge pressure were lowered by 10.5% when nanorefrigerant was used. The evaporator temperature was reduced by 6% with the use of nanorefrigerant. Hence ZnO nanoparticles could be used in refrigeration system to considerably reduce energy consumption. The usage of R152a with zero ozone depleting potential (ODP) and very less GWP and thus provides a green and clean environment. The complete experimental results and their analysis are reported in the main paper.

关键词： ZnO nanorefrigerant     reduced GWP     COP     pressure ratio green energy    

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标题 作者 时间 类型 操作

Spatial targeting evaluation of energy and environmental performance of waste-to-energy processing

Petar S. Varbanov, Timothy G. Walmsley, Yee V. Fan, Jiří J. Klemeš, Simon J. Perry

期刊论文

Energy neutrality potential of wastewater treatment plants: A novel evaluation framework integratingenergy efficiency and recovery

期刊论文

A Novel Electrochemical Reactor for Nitrogen and Phosphorus Recovery from Domestic Wastewater

Shiting Ren, Mengchen Li, Jianyu Sun, Yanhong Bian, Kuichang Zuo, Xiaoyuan Zhang, Peng Liang, Xia Huang

期刊论文

“NEW” resource recovery from wastewater using bioelectrochemical systems: Moving forward with functions

Akshay Jain, Zhen He

期刊论文

山西沁水盆地柿庄北区块3#煤层注入埋藏CO2提高煤层气采收率试验和评价

叶建平,张兵,Sam Wong

期刊论文

Improved energy recovery from dark fermented cane molasses using microbial fuel cells

Soumya Pandit, Balachandar G, Debabrata Das

期刊论文

Concentrating aqueous hydrochloric acid by multiple-effect membrane distillation

Rongling LIU, Yingjie QIN, Xiaojun LI, Liqiang LIU

期刊论文

Heating energy performance and part load ratio characteristics of boiler staging in an office building

Da Young LEE, Byeong Mo SEO, Yeo Beom YOON, Sung Hyup HONG, Jong Min CHOI, Kwang Ho LEE

期刊论文

Early-life famine exposure, adulthood obesity patterns, and risk of low-energy fracture

期刊论文

Co-application of energy uncoupling and ultrafiltration in sludge treatment: Evaluations of sludge reduction, supernatant recovery and membrane fouling control

An Ding, Yingxue Zhao, Zhongsen Yan, Langming Bai, Haiyang Yang, Heng Liang, Guibai Li, Nanqi Ren

期刊论文

农业生态工程中人工辅助能产投比的计算分析研究

卞有生,柳英昆,卞晶

期刊论文

Organics Recovery from Waste Activated Sludge In-situ Driving Efficient Nitrogen Removal from MatureLandfill Leachate: An Innovative Biotechnology with Energy Superiority

Fangzhai Zhang,Shang Ren,Haoran Liang,Zhaozhi Wang,Ying Yan,Jiahui Wang,Yongzhen Peng,

期刊论文

An investigation of reaction furnace temperatures and sulfur recovery

S. ASADI, M. PAKIZEH, M. POURAFSHARI CHENAR

期刊论文

On water security, sustainability, and the water-food-energy-climate nexus

Michael Bruce BECK, Rodrigo VILLARROEL WALKER

期刊论文

ZnO nanorefrigerant in R152a refrigeration system for energy conservation and green environment

D. SENDIL KUMAR,R. ELANSEZHIAN

期刊论文